![]() | Maria R. Coleman Professor of Chemical and Environmental Engineering |
Phone: (419) 530-8091, Fax: (419) 530-8086, E-mail: macolema@eng.utoledo.edu
Education
Research Interests
My research interests lie in the following three areas (i) investigation of post-formation surface modification techniques for development of gas separation membranes, (ii) investigation of the transport mechanism of small molecules within a glassy polymer matrix, and (iii) development of immobilized metal affinity membrane based separation systems for recovery of amino acids and proteins. The objective of the fundamental transport and surface modification studies is to develop a program for the synthesis of polymeric materials which act as permselective layers in barrier coatings for microelectronics and gas separation membranes. The objective of the metal affinity facilitated transport membrane projects are to modify of polymer gel membranes with fixed-site carriers to recover amino acids and proteins from solution based upon the selectivity of metal-protein interactions.
Selected Publications
M.R. Coleman and W.J. Koros, "The Transport Properties of Polyimide Isomers Containing Hexafluoroisopropylidene in the Diamine Residue," Journal of Polymer Science, Polymer Physics Ed., 32, 1915-1926, 1994.
S.A. Chai, R. R. Beitle, and M.R. Coleman, "Facilitated Transport Metal Affinity Membranes," International Journal of Biochromatography, 2, 125-131, 1996.
M.R. Coleman and W.J. Koros, "Conditioning of Fluorine Containing Polyimides, Part 1: Permeability Enhancement Following Exposure to High Pressure Carbon Dioxide," Macromolecules, 30, 6899-6905, 1997.
X. Xu and M.R. Coleman, "Atomic Force Microscopy Images of Ion Implanted 6FDA-pMDA Polyimide Films," Journal of Applied Polymer Science, 66, 459-469, 1997.
C. Oxford, A. Taylor, D. Crookston, R.R. Beitle, and M.R. Coleman, "Effect of Chelated Metal on Amino Acid Transport in Facilitated Transport Membranes Incorporating Metal Affinity," ACS Symposium Series on Membrane Materials and Formation, 1999.
X. Xu, U. Muler, P. Simpson and M.R. Coleman, "Post-Synthesis Method for Development of Membranes Using Ion Beam Irradiation of Polyimide Thins Films" ACS Symposium Series on Membrane Materials and Formation, 1999.Xu, X. and M.R. Coleman, "Preliminary Investigation of Gas Transport Mechanism in a H+ Irradiated Polyimide-Ceramic Composite Membrane," Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, 152, Issue: 2-3, 325-334, 1999.
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